@article{3c83cc276ddb47daba50d1744559dd4c,
title = "Revision of the structure of raphanusanins, phototropism-regulating substances of radish hypocotyls",
abstract = "The structures of raphanusanins A and B, growth inhibitors involved in phototropism of radish hypocotyls, were determined by X-ray crystallographic structure analysis and by spectral studies to be (3R*,6R*)- and (3R*,6S*)-3-[methoxy(methylthio)methyl]-2-pyrrolidinethione, respectively. Therefore, the previously proposed structure of these compounds of 2-piperidinethione skeleton should be revised.",
keywords = "X-ray structure analysis, growth inhibitor, phototropism, radish hypocotyls, raphanusanins A and B",
author = "Nobuyuki Harada and Hisahiro Hagiwara and Hiroshi Ono and Hisashi Uda and Shigeru Ohba and Mari Kubota and Shigeru Nishiyama and Shosuke Yamamura and Koji Hasegawa and Masako Sakoda",
note = "Funding Information: Acknowledgment. This work was supportedi n part by grants from the Ministry of Education, Science, and Culture, Japan (General (A) No. 59430005a nd General (B) No. 01470026t o N.H., and priority Areas Nos. 02250103a nd 03236101t o N.H., S.Y., and K.H.).",
year = "1991",
month = nov,
day = "11",
doi = "10.1016/S0040-4039(00)93595-0",
language = "English",
volume = "32",
pages = "6757--6760",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "46",
}