Revision of the structure of raphanusanins, phototropism-regulating substances of radish hypocotyls

Nobuyuki Harada, Hisahiro Hagiwara, Hiroshi Ono, Hisashi Uda, Shigeru Ohba, Mari Kubota, Shigeru Nishiyama, Shosuke Yamamura, Koji Hasegawa, Masako Sakoda

研究成果: Article

13 引用 （Scopus）

抜粋

The structures of raphanusanins A and B, growth inhibitors involved in phototropism of radish hypocotyls, were determined by X-ray crystallographic structure analysis and by spectral studies to be (3R*,6R*)- and (3R*,6S*)-3-[methoxy(methylthio)methyl]-2-pyrrolidinethione, respectively. Therefore, the previously proposed structure of these compounds of 2-piperidinethione skeleton should be revised.

元の言語English
ページ（範囲）6757-6760
ページ数4
ジャーナルTetrahedron Letters
巻32
発行部数46
DOI
出版物ステータスPublished - 1991 11 11

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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    Harada, N., Hagiwara, H., Ono, H., Uda, H., Ohba, S., Kubota, M., Nishiyama, S., Yamamura, S., Hasegawa, K., & Sakoda, M. (1991). Revision of the structure of raphanusanins, phototropism-regulating substances of radish hypocotyls. Tetrahedron Letters, 32(46), 6757-6760. https://doi.org/10.1016/S0040-4039(00)93595-0