Revision of the structure of raphanusanins, phototropism-regulating substances of radish hypocotyls

Nobuyuki Harada, Hisahiro Hagiwara, Hiroshi Ono, Hisashi Uda, Shigeru Ohba, Mari Kubota, Shigeru Nishiyama, Shosuke Yamamura, Koji Hasegawa, Masako Sakoda

研究成果: Article査読

13 被引用数 (Scopus)

抄録

The structures of raphanusanins A and B, growth inhibitors involved in phototropism of radish hypocotyls, were determined by X-ray crystallographic structure analysis and by spectral studies to be (3R*,6R*)- and (3R*,6S*)-3-[methoxy(methylthio)methyl]-2-pyrrolidinethione, respectively. Therefore, the previously proposed structure of these compounds of 2-piperidinethione skeleton should be revised.

本文言語English
ページ(範囲)6757-6760
ページ数4
ジャーナルTetrahedron Letters
32
46
DOI
出版ステータスPublished - 1991 11 11

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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