Rhodium-catalyzed anti-markovnikov addition of secondary amines to arylacetylenes at room temperature

研究成果: Article査読

36 被引用数 (Scopus)

抄録

An efficient method for synthesis of E-enamines by the anti-Markovnikov addition of secondary amines to terminal alkynes is described. The reaction of a variety of aryl- and heteroarylacetylenes proceeded at room temperature using a combination of a 8-quinolinolato rhodium complex and P(p-MeOC6H 4)3 as a catalyst. The products were obtained as enamines by simple bulb-to-bulb distillation.

本文言語English
ページ(範囲)3928-3931
ページ数4
ジャーナルOrganic Letters
13
15
DOI
出版ステータスPublished - 2011 8 5

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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