Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Aliphatic and Aromatic Terminal Alkynes with Aliphatic Primary Amines

Yoshihiko Morimoto, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Anti-Markovnikov hydroamination of both aliphatic and aromatic terminal alkynes with primary amines was achieved using an 8-quinolinolato rhodium catalyst to form aldimines and enamines in high yields. This catalytic system realized high functional group tolerance including hydroxy, bromo, cyano, and thioester groups.

本文言語English
ページ(範囲)13143-13152
ページ数10
ジャーナルJournal of Organic Chemistry
86
18
DOI
出版ステータスPublished - 2021 9月 17

ASJC Scopus subject areas

  • 有機化学

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