Rhodium-catalyzed anti-Markovnikov intermolecular hydroalkoxylation of terminal acetylenes

研究成果: Article査読

72 被引用数 (Scopus)

抄録

We report here the first transition-metal-catalyzed anti-Markovnikov intermolecular hydroalkoxylation of terminal acetylenes to give enol ethers in high yields without using bases. Arylacetylenes as well as alkenyl- and alkylacetylenes were coupled with aliphatic alcohols, and the products were obtained with high Z selectivity in most cases. Effective catalysts were 8-quinolinolato rhodium complexes, which are structurally simple but have been relatively unexplored as catalysts.

本文言語English
ページ(範囲)32-34
ページ数3
ジャーナルJournal of the American Chemical Society
133
1
DOI
出版ステータスPublished - 2011 1月 12

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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