Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group

Yutaka Ishii, Naoto Chatani, Fumitoshi Kakiuchi, Shinji Murai

研究成果: Article査読

42 被引用数 (Scopus)

抄録

The reaction of N-acylpiperazines with CO (15 atm) and ethylene at 160°C in the presence of Rh4(CO)12 results in dehydrogenation and carbonylation at a C-H bond. This reaction represents the first example of carbonylation at a C-H bond promoted by an oxygen functional group.

本文言語English
ページ(範囲)7565-7568
ページ数4
ジャーナルTetrahedron Letters
38
43
DOI
出版ステータスPublished - 1997 10 27
外部発表はい

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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