Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group

Yutaka Ishii; Naoto Chatani; Fumitoshi Kakiuchi; Shinji Murai

doi:10.1016/S0040-4039(97)01738-3

Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group

Yutaka Ishii, Naoto Chatani, Fumitoshi Kakiuchi, Shinji Murai

研究成果: Article › 査読

42 被引用数 (Scopus)

抄録

The reaction of N-acylpiperazines with CO (15 atm) and ethylene at 160°C in the presence of Rh₄(CO)₁₂ results in dehydrogenation and carbonylation at a C-H bond. This reaction represents the first example of carbonylation at a C-H bond promoted by an oxygen functional group.

本文言語	English
ページ（範囲）	7565-7568
ページ数	4
ジャーナル	Tetrahedron Letters
巻	38
号	43
DOI	https://doi.org/10.1016/S0040-4039(97)01738-3
出版ステータス	Published - 1997 10 27
外部発表	はい

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

文献へのアクセス

10.1016/S0040-4039(97)01738-3

他のファイルとリンク

フィンガープリント「Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{255bc376aeb94102a2741536ca67f432,

title = "Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group",

abstract = "The reaction of N-acylpiperazines with CO (15 atm) and ethylene at 160°C in the presence of Rh4(CO)12 results in dehydrogenation and carbonylation at a C-H bond. This reaction represents the first example of carbonylation at a C-H bond promoted by an oxygen functional group.",

author = "Yutaka Ishii and Naoto Chatani and Fumitoshi Kakiuchi and Shinji Murai",

note = "Funding Information: This work is partially supported by grants from the Ministry of Education, Science, and Culture, Japan.",

year = "1997",

month = oct,

day = "27",

doi = "10.1016/S0040-4039(97)01738-3",

language = "English",

volume = "38",

pages = "7565--7568",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "43",

}

TY - JOUR

T1 - Rhodium-catalyzed reaction of N-acylpiperazines with CO and ethylene. Carbonylation at a C-H bond directed by an amido group

AU - Ishii, Yutaka

AU - Chatani, Naoto

AU - Kakiuchi, Fumitoshi

AU - Murai, Shinji

N1 - Funding Information: This work is partially supported by grants from the Ministry of Education, Science, and Culture, Japan.

PY - 1997/10/27

Y1 - 1997/10/27

N2 - The reaction of N-acylpiperazines with CO (15 atm) and ethylene at 160°C in the presence of Rh4(CO)12 results in dehydrogenation and carbonylation at a C-H bond. This reaction represents the first example of carbonylation at a C-H bond promoted by an oxygen functional group.

AB - The reaction of N-acylpiperazines with CO (15 atm) and ethylene at 160°C in the presence of Rh4(CO)12 results in dehydrogenation and carbonylation at a C-H bond. This reaction represents the first example of carbonylation at a C-H bond promoted by an oxygen functional group.

UR - http://www.scopus.com/inward/record.url?scp=0030860516&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030860516&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(97)01738-3

DO - 10.1016/S0040-4039(97)01738-3

M3 - Article

AN - SCOPUS:0030860516

VL - 38

SP - 7565

EP - 7568

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 43

ER -