Rh4S7 and Ir3CuS6 clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes

Takuya Kochi; Yoshiaki Tanabe; Zhen Tang; Youichi Ishii; Masanobu Hidai

doi:10.1246/cl.1999.1279

Rh₄S₇ and Ir₃CuS₆ clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes

Takuya Kochi, Yoshiaki Tanabe, Zhen Tang, Youichi Ishii, Masanobu Hidai

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(μ-SH)₂MClCp*] (M = Rh, Ir) with CuCl₂·2H₂O lead to formation of Rh₄S₇ and Ir₃CuS₆ clusters [(Cp*Rh)₄(μ₃-S₂)₂(μ4-S₃)][[CuCl₂l₂ and [(Cp*Ir)₃(μ₃-S₂)₃(CuCl₂)][CuCl₂] through the oxidative S - S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ₄-η²:η¹:η¹:η¹ coordination mode.

本文言語	English
ページ（範囲）	1279-1280
ページ数	2
ジャーナル	Chemistry Letters
号	12
DOI	https://doi.org/10.1246/cl.1999.1279
出版ステータス	Published - 1999
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.1999.1279

他のファイルとリンク

引用スタイル

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title = "Rh4S7 and Ir3CuS6 clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes",

abstract = "Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(μ-SH)2MClCp*] (M = Rh, Ir) with CuCl2·2H2O lead to formation of Rh4S7 and Ir3CuS6 clusters [(Cp*Rh)4(μ3-S2)2(μ4-S3)][[CuCl2l2 and [(Cp*Ir)3(μ3-S2)3(CuCl 2)][CuCl2] through the oxidative S - S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ4-η2:η1:η1:η1 coordination mode.",

author = "Takuya Kochi and Yoshiaki Tanabe and Zhen Tang and Youichi Ishii and Masanobu Hidai",

year = "1999",

doi = "10.1246/cl.1999.1279",

language = "English",

pages = "1279--1280",

journal = "Chemistry Letters",

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T1 - Rh4S7 and Ir3CuS6 clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes

AU - Kochi, Takuya

AU - Tanabe, Yoshiaki

AU - Tang, Zhen

AU - Ishii, Youichi

AU - Hidai, Masanobu

PY - 1999

Y1 - 1999

N2 - Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(μ-SH)2MClCp*] (M = Rh, Ir) with CuCl2·2H2O lead to formation of Rh4S7 and Ir3CuS6 clusters [(Cp*Rh)4(μ3-S2)2(μ4-S3)][[CuCl2l2 and [(Cp*Ir)3(μ3-S2)3(CuCl 2)][CuCl2] through the oxidative S - S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ4-η2:η1:η1:η1 coordination mode.

AB - Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(μ-SH)2MClCp*] (M = Rh, Ir) with CuCl2·2H2O lead to formation of Rh4S7 and Ir3CuS6 clusters [(Cp*Rh)4(μ3-S2)2(μ4-S3)][[CuCl2l2 and [(Cp*Ir)3(μ3-S2)3(CuCl 2)][CuCl2] through the oxidative S - S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ4-η2:η1:η1:η1 coordination mode.

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