(R,R)-( - )-trans-1,4-Dioxaspiro[4,4]nonane-2,3-diylbis(diphenylmethanol)- N-allyl-N-propyl-3-oxocyclohexene-1-carboxamide (2/1)

Shigeru Ohba, Hisakazu Miyamoto

研究成果: Article査読

1 被引用数 (Scopus)

抄録

The enantioselective intramolecular photocyclization reaction of N-allyl-N-R-3-oxo-1-cyclohexenecarboxamides in inclusion crystals was studied. The products obtained were tricyclic compounds, as the results of a [2+2]-photoreaction in the guest molecule, except for that with R = nPr, which gave the spiro β-lactam (A), not the tricyclic compound (B). The crystal structure of the given compound is determined to investigate the conformation of the amide (R = nPr). It was observed that molecular structure of the amide compound is same as that observed in the inclusion compound with the corresponding six-membered ring host, differing only in the size of the cycloalkane ring.

本文言語English
ページ(範囲)o216-o218
ジャーナルActa Crystallographica Section E: Structure Reports Online
60
2
DOI
出版ステータスPublished - 2004 2 1

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

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「(R,R)-( - )-trans-1,4-Dioxaspiro[4,4]nonane-2,3-diylbis(diphenylmethanol)- N-allyl-N-propyl-3-oxocyclohexene-1-carboxamide (2/1)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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