抄録
The RuH2(CO)(PPh3)3-catalyzed C-H functionalization of aromatic esters with 5,5-dimethyl-2-aryl-[1,3,2]dioxaborinanes (arylboronates) gave the ortho arylation products. This coupling reaction can be performed with various combinations of isopropyl benzoate derivatives and arylboronates. Introduction of CF3 group in the aromatic ring increased the reactivity of the esters. Pinacolone effectively served as an acceptor of a hydride generated by C-H bond cleavage, and the amount of pinacolone used also affected the yield of the arylation product.
本文言語 | English |
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ページ(範囲) | 1163-1167 |
ページ数 | 5 |
ジャーナル | Journal of Organometallic Chemistry |
巻 | 695 |
号 | 8 |
DOI | |
出版ステータス | Published - 2010 4月 15 |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学
- 無機化学
- 材料化学