抄録
A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 109-110 |
| ページ数 | 2 |
| ジャーナル | Chemistry Letters |
| 発行部数 | 2 |
| 出版物ステータス | Published - 1996 |
| 外部発表 | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
これを引用
Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins. / Sonoda, Motohiro; Kakiuchi, Fumitoshi; Kamatani, Asayuki; Chatani, Naoto; Murai, Shinji.
：: Chemistry Letters, 番号 2, 1996, p. 109-110.研究成果: Article
}
TY - JOUR
T1 - Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins
AU - Sonoda, Motohiro
AU - Kakiuchi, Fumitoshi
AU - Kamatani, Asayuki
AU - Chatani, Naoto
AU - Murai, Shinji
PY - 1996
Y1 - 1996
N2 - A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.
AB - A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.
UR - http://www.scopus.com/inward/record.url?scp=0030532360&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030532360&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030532360
SP - 109
EP - 110
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 2
ER -