Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

Motohiro Sonoda; Fumitoshi Kakiuchi; Asayuki Kamatani; Naoto Chatani; Shinji Murai

doi:10.1246/cl.1996.109

Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

Motohiro Sonoda, Fumitoshi Kakiuchi, Asayuki Kamatani, Naoto Chatani, Shinji Murai

研究成果: Article › 査読

107 被引用数 (Scopus)

抄録

A ruthenium complex, Ru(H)₂(CO)(PPh₃)₃, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF₃ or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.

本文言語	English
ページ（範囲）	109-110
ページ数	2
ジャーナル	Chemistry Letters
号	2
DOI	https://doi.org/10.1246/cl.1996.109
出版ステータス	Published - 1996 1月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.1996.109

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abstract = "A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.",

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AU - Murai, Shinji

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AB - A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.

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Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

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