Ruthenium-catalyzed conversion of sp3 C-O bonds in ethers to C-C bonds using triarylboroxines

研究成果: Article査読

32 被引用数 (Scopus)

抄録

Catalytic conversion of unreactive sp3 C-O bonds in alkyl ethers to C-C bonds is described. Alkyl ethers bearing 2- or 4-pyridyl groups were coupled with triarylboroxines in the presence of a ruthenium catalyst. Triarylboroxines bearing a variety of functional groups including electron-withdrawing and -donating groups can be used for the reaction. No additional base was required for the coupling with the organoboron reagents, and base-sensitive groups can be tolerated. The reaction is considered to proceed via dehydroalkoxylation followed by addition of triarylboroxines to form C-C bonds.

本文言語English
ページ(範囲)3254-3257
ページ数4
ジャーナルOrganic Letters
13
12
DOI
出版ステータスPublished - 2011 6 17

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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