Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage

Fumitoshi Kakiuchi, Kimitaka Igi, Mitsutaka Matsumoto, Naoto Chatani, Shinji Murai

研究成果: Article査読

94 被引用数 (Scopus)

抄録

The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.

本文言語English
ページ(範囲)422-423
ページ数2
ジャーナルChemistry Letters
5
DOI
出版ステータスPublished - 2001
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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