Ruthenium-catalyzed reactions of acyclic α,β-enones with olefins and their reaction mechanisms

Taisuke Sato, Fumitoshi Kakiuchi, Naoto Chatani, Shinji Murai

研究成果: Article査読

64 被引用数 (Scopus)

抄録

The reaction of 4,4-dimethyl-5-phenyl-4-peneten-3-one with styrene (2) using Ru(H)2(CO)(PPh3)3 as the catalyst gave the stereochemically retained product. In the case of 2,2-dimethyl-4-hexen-3-one, the stereochemically inverted branched product was obtained. These results are consistent with two different reaction pathways operating, i.e. one involving a direct C-H bond cleavage and the other, a pathway involving hydrometallation.

本文言語English
ページ(範囲)893-894
ページ数2
ジャーナルChemistry Letters
9
DOI
出版ステータスPublished - 1998 1月 1
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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