Ruthenium-catalyzed reductive deamination and tandem alkylation of aniline derivatives

研究成果: Article

19 引用 (Scopus)

抜粋

We developed two new catalytic transformations of anilines via oxidative addition of CeN bonds to ruthenium centers. One is ruthenium-catalyzed reductive deaminatoindeamination of N-alkylated oacylanilines. The other one is catalytic coupling of N-alkylated o-acylanilines with olefins giving orthoalkylated aromatic ketones via CeN bond cleavage. This reaction involves a ruthenium hydride species as an intermediate, formed after b-hydride elimination from the ruthenium amide species.

元の言語English
ページ(範囲)148-152
ページ数5
ジャーナルJournal of Organometallic Chemistry
741-742
発行部数1
DOI
出版物ステータスPublished - 2013 1 1

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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