Selective Long-Distance Isomerization of Terminal Alkenes via Nondissociative Chain Walking

Yuya Yamasaki, Takaaki Kumagai, Shota Kanno, Fumitoshi Kakiuchi, Takuya Kochi

研究成果: Article査読

18 被引用数 (Scopus)

抄録

Selective long-distance isomerization of terminal alkenes to silyl enol ethers proceeded via nondissociative chain walking using phenanthroline palladium catalysts. Notable features achieved taking advantage of the nondissociative chain walking mechanism include high efficiency obtained regardless of the chain length, high chemoselectivity toward terminal alkenes over internal ones, and retention of the stereoconfiguration of the stereocenter on the alkyl chain.

本文言語English
ページ(範囲)9322-9333
ページ数12
ジャーナルJournal of Organic Chemistry
83
16
DOI
出版ステータスPublished - 2018 8月 17

ASJC Scopus subject areas

  • 有機化学

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