TY - JOUR
T1 - Selective molecular absorption from low molecular weight mixed solution to a polymer p4mp1 film
AU - Chiba, Ayano
AU - Akiyama, Ryo
N1 - Publisher Copyright:
© 2021, Japan Society of High Pressure Science and Technology. All rights reserved.
PY - 2021
Y1 - 2021
N2 - Recently isotactic poly(4-methyl-1-pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained.
AB - Recently isotactic poly(4-methyl-1-pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained.
KW - Asakura-Oosawa theory
KW - Host-guest structures
KW - Melting curve maximum
KW - Molecular recognition
KW - P4MP1
KW - PMP
KW - Selective absorption
KW - SPS
UR - http://www.scopus.com/inward/record.url?scp=85118178477&partnerID=8YFLogxK
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U2 - 10.4131/jshpreview.31.82
DO - 10.4131/jshpreview.31.82
M3 - Article
AN - SCOPUS:85118178477
SN - 0917-639X
VL - 31
SP - 82
EP - 89
JO - Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
JF - Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
IS - 2
ER -