Selective synthesis of C 3 symmetric functionalized sumanenes

Shuhei Higashibayashi, R. B. Nasir Baig, Yuki Morita, Hidehiro Sakurai

研究成果: Article

21 引用 (Scopus)

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C 3 symmetric triformylsumanene was selectively synthesized from C 3 symmetric syn-tris(oxonorborneno)benzene, featuring ring-opening/closing metathesis reactions of syntris( methoxymethylnorbornadieno)benzene and DDQ oxidation. Triformylsumanene can be an intermediate to synthesize C 3 symmetric trisubstituted sumanenes by further transformation. Tris(ethoxycarbonylethenyl)sumanene was prepared through the HornerWadsworthEmmons reaction. Its optical and electrochemical behaviors were investigated.

元の言語English
ページ(範囲)84-86
ページ数3
ジャーナルChemistry Letters
41
発行部数1
DOI
出版物ステータスPublished - 2012 1 6
外部発表Yes

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ASJC Scopus subject areas

  • Chemistry(all)

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