Silver-catalyzed incorporation of carbon dioxide into o-alkynylaniline derivatives

Tomonobu Ishida, Satoshi Kikuchi, Tatsuyuki Tsubo, Tohru Yamada

研究成果: Article査読

119 被引用数 (Scopus)

抄録

Benzoxazine-2-one derivatives are important heterocycle structures because of their various pharmaceutical activities, though their synthetic methods had been limited. In some cases, toxic reagents, such as phosgene or carbon monoxide, are required. It was found that a silver catalyst successfully promoted the incorporation of CO2 into o-alkynylanilines to afford the corresponding benzoxazine-2-ones bearing Z exo-olefin via 6-exo-dig cyclization at the activated C-C triple bond.

本文言語English
ページ(範囲)848-851
ページ数4
ジャーナルOrganic Letters
15
4
DOI
出版ステータスPublished - 2013 2月 15

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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