Silver-catalyzed incorporation of carbon dioxide into propargylic alcohols

Wataru Yamada, Yudai Sugawara, Man Cheng Hau, Taketo Ikeno, Tohru Yamada

研究成果: Article査読

166 被引用数 (Scopus)

抄録

The combined use of a catalytic amount of silver acetate and a stoichiometric amount of DBU efficiently catalyzed the incorporation of CO 2 under mild reaction conditions into a wide range of propargylic alcohols bearing a terminal or an internal triple bond to afford the corresponding cyclic carbonates in high-to-excellent yields. All the cyclic carbonates obtained from the reaction were found to be single isomers. The geometries were determined to be (Z) by X-ray crystal structure analysis and NOE experiments.

本文言語English
ページ(範囲)2604-2607
ページ数4
ジャーナルEuropean Journal of Organic Chemistry
16
DOI
出版ステータスPublished - 2007 6 22

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学

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