Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

研究成果: Article

29 引用 (Scopus)

抄録

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

元の言語English
ページ(範囲)2033-2036
ページ数4
ジャーナルOrganometallics
18
発行部数10
出版物ステータスPublished - 1999 5 10
外部発表Yes

Fingerprint

Styrenes
Ruthenium
Alkenes
Carbon Monoxide
acrylates
styrenes
ruthenium
alkenes
ethers
methyl acrylate
vinylsilane
allylsilane
vinyl ether

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

これを引用

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abstract = "Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.",
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N2 - Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

AB - Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

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