Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Fumitoshi Kakiuchi, Airi Yamada, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

研究成果: Article

30 引用 (Scopus)

抜粋

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh 3 ) 3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

元の言語English
ページ(範囲)2033-2036
ページ数4
ジャーナルOrganometallics
18
発行部数10
DOI
出版物ステータスPublished - 1999 5 10
外部発表Yes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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