Solid-state and solution photolyses of tetracyanobenzene with benzyl cyanides or benzyl alcohols

Yoshikatsu Ito, Hironari Nakabayashi, Shigeru Ohba, Hiroyuki Hosomi

研究成果: Article査読

9 被引用数 (Scopus)

抄録

Intermolecular photoreactions of tetracyanobenzene (TCNB) with benzyl cyanide (BzCN), benzyl alcohol (BzOH) and various others were investigated in the solid state (cocrystal) and in solution. The new solid-state photocoupling reaction found for the cocrystal TCNB·BzCN, giving a stilbene derivative followed by the solution isomerization into an isoindole derivative, is a very limited reaction. On the other hand, its solution photocondensation to give products of the diphenylmethane type occurred quite generally, probably under acidic conditions. (C) 2000 Elsevier Science Ltd.

本文言語English
ページ(範囲)7139-7152
ページ数14
ジャーナルTetrahedron
56
37
DOI
出版ステータスPublished - 2000 9月 8

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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