Solid-state 17O NMR analysis of synthetically 17O-enriched D-glucosamine

Kazuhiko Yamada, Yoshiki Yamaguchi, Yoshinori Uekusa, Kazumasa Aoki, Ichio Shimada, Takumi Yamaguchi, Koichi Kato

研究成果: Article査読


The hydroxyl groups of carbohydrates are critical determinants of their conformational dynamics and intermolecular interactions but are difficult to characterize by conventional 1H nuclear magnetic resonance (NMR) approaches in solution. Here, we report a solid-state 17O NMR analysis of synthetic glucosamine with 17O enrichment at position 6. Based on magic-angle spinning and stationary spectral data obtained at varying magnetic fields in conjunction with quantum chemical calculations, we successfully estimated 17O chemical shift and electric field gradient tensors, providing benchmark for 17O NMR analyses of oligosaccharide structures.

ジャーナルChemical Physics Letters
出版ステータスPublished - 2020 6 16

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

フィンガープリント 「Solid-state <sup>17</sup>O NMR analysis of synthetically <sup>17</sup>O-enriched D-glucosamine」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。