Stereocontrolled Photoinduced Glycosylation Using an Aryl Thiourea as an Organo photoacid

Tomoya Kimura, Takahiro Eto, Daisuke Takahashi, Kazunobu Toshima

研究成果: Article査読

54 被引用数 (Scopus)

抄録

Photoinduced glycosylation of alcohols with α-glucosyl trichloroacetimidates, using aryl urea and thioureas as organo photoacids, was examined under long wavelength UV (ultraviolet) irradiation. The results show, for the first time, that such glycosylations proceed effectively to give the corresponding glycosides in high yields. In addition, high β-stereoselectivity was obtained under high concentration conditions, whereas high α-stereoselectivity was realized under low concentration conditions.

本文言語English
ページ(範囲)3190-3193
ページ数4
ジャーナルOrganic Letters
18
13
DOI
出版ステータスPublished - 2016 7 1

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

フィンガープリント

「Stereocontrolled Photoinduced Glycosylation Using an Aryl Thiourea as an Organo photoacid」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル