Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A

Akihiro Sakama, Yoshiyasu Nishimura, Yuko Motohashi, Keisuke Yoshida, Kenichi Takao

研究成果: Article

2 引用 (Scopus)

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Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes is described. Sugar-derived aldehydes were allylated with geranylboronate or nerylboronate to provide γ-adducts possessing quaternary stereocenters with high diastereoselectivity. The reaction was applied to the synthesis of a fragment of (+)-vibsanin A.

元の言語English
ページ(範囲)5465-5471
ページ数7
ジャーナルTetrahedron
72
発行部数35
DOI
出版物ステータスPublished - 2016 9 1

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ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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