Stereoselective conversion of l-quebrachitol into a novel hydroxylated caprolactam: Total synthesis of bengamide B

Noritaka Chida, Takahiko Tobe, Katsuyuki Murai, Kaori Yamazaki, Seiichiro Ogawa

研究成果: Article査読

36 被引用数 (Scopus)

抄録

The stereoselective synthesis of the novel marine natural product, bengamide B (1), starting from l-quebrachitol (3) is described. The hydroxylated caprolactam portion (2a) in 1 was prepared from (+)-conduramine derivative (7), whose amino functionality was introduced stereoselectively by means of palladium-catalyzed azidation of a chiral cyclohexene (6) derived from 3.

本文言語English
ページ(範囲)2383-2388
ページ数6
ジャーナルHeterocycles
38
11
DOI
出版ステータスPublished - 1994 11 1

ASJC Scopus subject areas

  • 分析化学
  • 薬理学
  • 有機化学

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