Stereoselective glycosylation using the long-range effect of a [2-(4-phenylbenzyl)oxycarbonyl]benzoyl group

Hiroomi Tokimoto, Yukari Fujimoto, Koichi Fukase, Shoichi Kusumoto

研究成果: Article査読

37 被引用数 (Scopus)

抄録

Highly α-selective glucosylation was effected by virtue of the solvent effect of cyclopentyl methyl ether and the long-range assistance of bulky 6-O-protective groups. Higher α-selectivity was obtained by the use of this solvent in comparison to conventional diethyl ether. α-Selectivity was further improved with the influence of 6-O-substituents, such as TBDPS and phthaloyl groups, the latter being mono esterified with a bulky alcohol.

本文言語English
ページ(範囲)441-447
ページ数7
ジャーナルTetrahedron Asymmetry
16
2
DOI
出版ステータスPublished - 2005 1月 24
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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