Stress-induced ligand field distribution and consequent multi-mode spin crossover in FeII(phen)2(NCS)2 and FeII[HB(pz)3]2

Naoko Tsuchiya, Atsushi Tsukamoto, Tadashi Ohshita, Tetsuhiko Isobe, Mamoru Senna, Naoki Yoshioka, Hidenari Inoue

研究成果: Article査読

20 被引用数 (Scopus)

抄録

Changes in the nature of spin crossover caused by mechanical stressing exerted on the crystalline powders were studied for FeII(phen)2(NCS)2 (phen = 1,10-phenanthroline) and FeII[HB(pz)3]2 (pz = pyrazol-1-yl) by means of a multi-component fitting of the temperature dependence of magnetic susceptibility. The analysis revealed the development and broadening of the ligand field distribution as a consequence of mechanical stressing. This was confirmed by the broadening of Mössbauer and far-infrared spectra.

本文言語English
ページ(範囲)705-714
ページ数10
ジャーナルSolid State Sciences
3
6
DOI
出版ステータスPublished - 2001

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

フィンガープリント 「Stress-induced ligand field distribution and consequent multi-mode spin crossover in Fe<sup>II</sup>(phen)<sub>2</sub>(NCS)<sub>2</sub> and Fe<sup>II</sup>[HB(pz)<sub>3</sub>]<sub>2</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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