Structural characterization of room-temperature synthesized fullerene nanowhiskers

Kun'ichi Miyazawa, Jun Ichi Minato, Tadahiko Mashino, Shigeo Nakamura, Masahisa Fujino, Tadatomo Suga

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Structural properties of various kinds of room-temperature synthesized C60 fullerene nanowhiskers were investigated by TEM and XRD. The C60 nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C60 nanowhiskers prepared by use of m-xylene. The hexagonal structure of C60 nanowhiskers prepared by use of toluene was stabilized by adding C 60[C(COOC2H5)2]. These results suggest that large solute molecules in the C60 nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C60(2-methoxycarbonyl-N- methylpyrrolidine) into the m-xylene solution of C60 produced the C60 nanowhiskers indicating the formation of ordered solid solution of C60 and C60(2-methoxycarbonyl-N-methylpyrrolidine).

本文言語English
ページ(範囲)S41-S48
ジャーナルNukleonika
51
SUPPL. 1
出版ステータスPublished - 2006 6月 14

ASJC Scopus subject areas

  • 核物理学および高エネルギー物理学
  • 原子力エネルギーおよび原子力工学
  • 器械工学
  • 安全性、リスク、信頼性、品質管理
  • 凝縮系物理学
  • 廃棄物管理と処理

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