Structural characterization of room-temperature synthesized fullerene nanowhiskers

Kun'ichi Miyazawa; Jun Ichi Minato; Tadahiko Mashino; Shigeo Nakamura; Masahisa Fujino; Tadatomo Suga

Structural characterization of room-temperature synthesized fullerene nanowhiskers

Kun'ichi Miyazawa, Jun Ichi Minato, Tadahiko Mashino, Shigeo Nakamura, Masahisa Fujino, Tadatomo Suga

薬科学科

研究成果: Article

10 引用（Scopus）

抜粋

Structural properties of various kinds of room-temperature synthesized C₆₀ fullerene nanowhiskers were investigated by TEM and XRD. The C₆₀ nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C₆₀ nanowhiskers prepared by use of m-xylene. The hexagonal structure of C₆₀ nanowhiskers prepared by use of toluene was stabilized by adding C ₆₀[C(COOC₂H₅)₂]. These results suggest that large solute molecules in the C₆₀ nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C₆₀(2-methoxycarbonyl-N- methylpyrrolidine) into the m-xylene solution of C₆₀ produced the C₆₀ nanowhiskers indicating the formation of ordered solid solution of C₆₀ and C₆₀(2-methoxycarbonyl-N-methylpyrrolidine).

元の言語	English
ページ（範囲）	S41-S48
ジャーナル	Nukleonika
巻	51
発行部数	SUPPL. 1
出版物ステータス	Published - 2006 6 14

ASJC Scopus subject areas

Nuclear and High Energy Physics
Nuclear Energy and Engineering
Instrumentation
Safety, Risk, Reliability and Quality
Condensed Matter Physics
Waste Management and Disposal

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Miyazawa, K., Minato, J. I., Mashino, T., Nakamura, S., Fujino, M., & Suga, T. (2006). Structural characterization of room-temperature synthesized fullerene nanowhiskers. Nukleonika, 51(SUPPL. 1), S41-S48.

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title = "Structural characterization of room-temperature synthesized fullerene nanowhiskers",

abstract = "Structural properties of various kinds of room-temperature synthesized C60 fullerene nanowhiskers were investigated by TEM and XRD. The C60 nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C60 nanowhiskers prepared by use of m-xylene. The hexagonal structure of C60 nanowhiskers prepared by use of toluene was stabilized by adding C 60[C(COOC2H5)2]. These results suggest that large solute molecules in the C60 nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C60(2-methoxycarbonyl-N- methylpyrrolidine) into the m-xylene solution of C60 produced the C60 nanowhiskers indicating the formation of ordered solid solution of C60 and C60(2-methoxycarbonyl-N-methylpyrrolidine).",

keywords = "C, Carbon, Fullerene, Nanowhisker, Structure, TEM",

author = "Kun'ichi Miyazawa and Minato, {Jun Ichi} and Tadahiko Mashino and Shigeo Nakamura and Masahisa Fujino and Tadatomo Suga",

year = "2006",

month = jun,

day = "14",

language = "English",

volume = "51",

pages = "S41--S48",

journal = "Nukleonika",

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TY - JOUR

T1 - Structural characterization of room-temperature synthesized fullerene nanowhiskers

AU - Miyazawa, Kun'ichi

AU - Minato, Jun Ichi

AU - Mashino, Tadahiko

AU - Nakamura, Shigeo

AU - Fujino, Masahisa

AU - Suga, Tadatomo

PY - 2006/6/14

Y1 - 2006/6/14

N2 - Structural properties of various kinds of room-temperature synthesized C60 fullerene nanowhiskers were investigated by TEM and XRD. The C60 nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C60 nanowhiskers prepared by use of m-xylene. The hexagonal structure of C60 nanowhiskers prepared by use of toluene was stabilized by adding C 60[C(COOC2H5)2]. These results suggest that large solute molecules in the C60 nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C60(2-methoxycarbonyl-N- methylpyrrolidine) into the m-xylene solution of C60 produced the C60 nanowhiskers indicating the formation of ordered solid solution of C60 and C60(2-methoxycarbonyl-N-methylpyrrolidine).

AB - Structural properties of various kinds of room-temperature synthesized C60 fullerene nanowhiskers were investigated by TEM and XRD. The C60 nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C60 nanowhiskers prepared by use of m-xylene. The hexagonal structure of C60 nanowhiskers prepared by use of toluene was stabilized by adding C 60[C(COOC2H5)2]. These results suggest that large solute molecules in the C60 nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C60(2-methoxycarbonyl-N- methylpyrrolidine) into the m-xylene solution of C60 produced the C60 nanowhiskers indicating the formation of ordered solid solution of C60 and C60(2-methoxycarbonyl-N-methylpyrrolidine).

KW - C

KW - Carbon

KW - Fullerene

KW - Nanowhisker

KW - Structure

KW - TEM

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VL - 51

SP - S41-S48

JO - Nukleonika

JF - Nukleonika

SN - 0029-5922

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