Structure and reactivity of bimetallic ConVm+ cluster ions

Atsushi Nakajima, Takashi Kishi, Tsuneyoshi Sugioka, Yasutomo Sone, Koji Kaya

研究成果: Article査読

28 被引用数 (Scopus)

抄録

The reaction of bimetallic ConVm+ cluster ions, generated by laser vaporization, toward hydrogen was investigated by using a fast-flow reactor. Compared with pure Con+ cluster ions, the reactivity of Con-1V+ cluster ions exhibits a drastic decrease at n ≥ 13 similar to that of neutral ConVm clusters. The result can be explained in terms of their geometrical structure; at n ≥ 13, the V atom is located at the center of the cluster and is surrounded by Co atoms.

本文言語English
ページ(範囲)6833-6835
ページ数3
ジャーナルJournal of Physical Chemistry
95
18
DOI
出版ステータスPublished - 1991 1月 1

ASJC Scopus subject areas

  • 工学(全般)
  • 物理化学および理論化学

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