Studies of the anisotropic diffusive motion of nanoparticlesat the solid-liquid interface using near-fieldfluorescence correlation spectroscopy

Motohiko Suzuki, Hiroki Kurihara, Toshiharu Saiki

    研究成果: Article査読

    抄録

    Near-field fluorescence correlation spectroscopy measurements of 20 and 40nm polystyrene nanoparticles were performed, using fiber probes with aperture diameters ranging from 100 to 250 nm. The experimental data were best fit by a two-dimensional diffusion model, implying that there was significant anisotropy associated with the movement of the particles, such that mobility normal to the wall was much lower than that parallel to the wall. Interestingly, the lateral diffusion coefficients were approximately ten times greater than predicted from the Stokes-Einstein relationship corrected by taking into account hydrodynamic drag forces due to particle-wall interactions. This discrepancy between experimental and theoretical results is possibly due to strong viscous forces as well as attractive forces at the interface.

    本文言語English
    ページ(範囲)376-379
    ページ数4
    ジャーナルElectrochemistry
    82
    5
    DOI
    出版ステータスPublished - 2014 5

    ASJC Scopus subject areas

    • Electrochemistry

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