Sumanenylferrocenes and their solid state self-assembly

Berit Topolinski; Bernd M. Schmidt; Shuhei Higashibayashi; Hidehiro Sakurai; Dieter Lentz

doi:10.1039/c3dt51569a

Sumanenylferrocenes and their solid state self-assembly

Berit Topolinski, Bernd M. Schmidt, Shuhei Higashibayashi, Hidehiro Sakurai, Dieter Lentz

研究成果: Article › 査読

15 被引用数 (Scopus)

抄録

The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C₂₁H₁₂) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

本文言語	English
ページ（範囲）	13809-13812
ページ数	4
ジャーナル	Dalton Transactions
巻	42
号	38
DOI	https://doi.org/10.1039/c3dt51569a
出版ステータス	Published - 2013 10月 14
外部発表	はい

ASJC Scopus subject areas

無機化学

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10.1039/c3dt51569a

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AB - The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

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Sumanenylferrocenes and their solid state self-assembly

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