Surface alloy formation at the Sm Ru(001) interface: evidence from Ru 3d core-level emission

G. Ranga Rao, Y. Kadowaki, H. Kondoh, H. Nozoye

研究成果: Article査読

16 被引用数 (Scopus)

抄録

Vapor deposited Sm on a Ru(001) surface at 500 K has been investigated by X-ray photoelectron spectroscopy (XPS), temperature programmed desorption spectroscopy (TPD) and work function measurements. The development of a first monolayer can be described as simple adsorption of Sm on the Ru(001) surface. At higher coverages, intermixing of Sm and Ru occurs leading to the formation of a SmRu alloy. The formation of an interfacial alloy above 1 ML coverage is confirmed by Ru 3d core-level photoemission. The average valency of Sm in the alloy phase is determined. Temperature dependent experiments indicate the formation of two alloy phases at the 400-700 and 700-800 K regions. TPD data indicate the zero-order desorption of Sm. Work function changes show that there is a significant amount of charge transfer from Sm atoms to the Ru substrate at low coverages.

本文言語English
ページ(範囲)293-300
ページ数8
ジャーナルSurface Science
327
3
DOI
出版ステータスPublished - 1995 4 10
外部発表はい

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

フィンガープリント 「Surface alloy formation at the Sm Ru(001) interface: evidence from Ru 3d core-level emission」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル