Surface-monolayer-controlled molecular alignment of short n-alkane multilayers

H. Kondoh, F. Matsui, Y. Ehara, T. Yokoyama, T. Ohta

研究成果: Article査読

23 被引用数 (Scopus)

抄録

C K-edge near-edge X-ray absorption fine structure studies have been performed on the molecular orientation of short n-alkane (C6H14) multilayers on n-alkanethiolate (C6H13S) monolayers. We have found that the molecular orientation of the n-alkane multilayers is in accordance with that of n-alkanethiolate monolayers on which the multilayers were formed. Monolayers of thiophene also have a significant effect on the alignment of the n-alkane multilayers condensed on the monolayers. The growth manner of the n-alkane films is discussed in terms of the energy balance between surface and interface free energies.

本文言語English
ページ(範囲)8178-8183
ページ数6
ジャーナルLangmuir
17
26
DOI
出版ステータスPublished - 2001 12 25
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

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