Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto, Hirofumi Iwamoto, Masaaki Kojima, Shigeru Ohba

研究成果: Conference article査読

1 被引用数 (Scopus)

抄録

Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

本文言語English
ページ(範囲)33-38
ページ数6
ジャーナルMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
376
DOI
出版ステータスPublished - 2002
イベントProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
継続期間: 2000 12 152000 12 18

ASJC Scopus subject areas

  • 凝縮系物理学

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