Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical

Yusuke Takahashi, Youhei Miura, Naoki Yoshioka

研究成果: Article査読

23 被引用数 (Scopus)

抄録

A novel benzotriazinyl radical, 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl (2), was prepared and its magneto-structural correlation was investigated. An X-ray crystallographic analysis revealed that 2 forms a 1D column assembly, however, π-π interaction was not the driving force of the column structure. The magnetic susceptibility obeyed the Curie-Weiss law with C = 0.369 emu K mol-1 and = +0.7 K. The thermal behavior of χmT was described using the 1D ferromagnetic chain model with J/kB = +0.91 K.

本文言語English
ページ(範囲)4783-4789
ページ数7
ジャーナルNew Journal of Chemistry
39
6
DOI
出版ステータスPublished - 2015 6月 1

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 材料化学

フィンガープリント

「Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル