Synthesis of α- and/or γ-benzoyloxy-α,β-enones from α-halo-α,β-enones

Yujiro Hayashi, Mitsuru Shoji, Satoshi Kishida

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Sodium benzoate reacts with α-halo-α,β-enones in the presence of tetrabutylammonium hydrogensulfate or 18-Crown-6 to afford α- and/or γ-benzoyloxylated α,β-enones in good yield. The α/γ and γ/γ′ selectivities are dependent on the substrate and reagent. Sodium benzoate reacts with α-halo-α,β- enones in the presence of tetrabutylammonium hydrogensulfate or 18-Crown-6 to afford α- and/or γ-benzoyloxy-α,β-enones in good yield. The α/γ and γ/γ′ selectivities are dependent on the substrate and reagent.

本文言語English
ページ(範囲)681-685
ページ数5
ジャーナルTetrahedron Letters
46
4
DOI
出版ステータスPublished - 2005 1 24

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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