Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure

Toru Amaya, Daisuke Takahashi, Hiroshi Tanaka, Takashi Takahashi

研究成果: Article

13 引用 (Scopus)

抄録

A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.

元の言語English
ページ(範囲)1833-1836
ページ数4
ジャーナルAngewandte Chemie - International Edition
42
発行部数16
DOI
出版物ステータスPublished - 2003 4 25
外部発表Yes

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sulfoxide
Disaccharides
Cyclization
Chemical activation

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

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abstract = "A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.",
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AU - Amaya, Toru

AU - Takahashi, Daisuke

AU - Tanaka, Hiroshi

AU - Takahashi, Takashi

PY - 2003/4/25

Y1 - 2003/4/25

N2 - A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.

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KW - Chemoselectivity

KW - Cyclization

KW - Glycosylation

KW - Oligosaccharides

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