Synthesis of an enantiopure syn-benzocyclotrimer through regio-selective cyclotrimerization of a halonorbornene derivative under palladium nanocluster conditions

Shuhei Higashibayashi, Hidehiro Sakurai

研究成果: Article査読

33 被引用数 (Scopus)

抄録

An enantiopure syn-benzocyclotrimer 1 was selectively synthesized from an enantiopure halonorbornene 2 through regioselective cyclotrimerization catalyzed by palladium nanoclusters. The yield of 1 was dependent on the stability of the palladium clusters, which was ascertained from the appearance and TEM images of the reaction mixtures. The thus-prepared enantiopure benzocyclotrimer will serve as a key intermediate for the synthesis of C3v symmetric chiral buckybowls.

本文言語English
ページ(範囲)18-19
ページ数2
ジャーナルChemistry Letters
36
1
DOI
出版ステータスPublished - 2007 1月 5
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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