Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization

Takuya Kochi, Kenji Yoshimura, Kyoko Nozaki

研究成果: Article査読

72 被引用数 (Scopus)

抄録

The synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization are examined. The methylpalladium complexes are frequently used for mechanistic investigation of the copolymerization. The copolymerization of ethylene and methyl acrylate with the catalysts is examined, and the effects of additives on the catalytic activity are found. The preliminary copolymerization results indicate that further examination of additives, ligands, bases used to prepare the catalysts, and reaction conditions would lead to an improved catalyst system for production of the unique highly linear copolymer of ethylene and methyl acrylate.

本文言語English
ページ(範囲)25-27
ページ数3
ジャーナルDalton Transactions
1
DOI
出版ステータスPublished - 2006 4月 10
外部発表はい

ASJC Scopus subject areas

  • 無機化学

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