Synthesis of hexopyranosyl acetates and 2,3-disubstituted tetrahydropyrans via chemoselective hydrogenation of hex-2-enopyranosyl acetates

Kaname Sasaki, Takayuki Wakamatsu, Shuichi Matsumura, Kazunobu Toshima

研究成果: Article査読

9 被引用数 (Scopus)

抄録

A simple and easy method for chemoselective synthesis of hexopyranosyl acetates and 2,3-disubstituted tetrahydropyrans from hex-2-enopyranosyl acetates was demonstrated. The former was achieved by hydrogenation catalyzed by Rh/Al2O3 in EtOAc/toluene solvent at 0 °C, while the latter was carried out using Pd/C in EtOH/AcOH at 25 °C.

本文言語English
ページ(範囲)8271-8274
ページ数4
ジャーナルTetrahedron Letters
47
47
DOI
出版ステータスPublished - 2006 11月 20

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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