Synthesis of methyl epi-anhydroquinate utilizing [2,3]-sigmatropic rearrangement of iodosoalkene

Sho Inomata, Minoru Ueda, Takeshi Sugai, Mitsuru Shoji

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Sigmatropic rearrangement has been utilized for stereoselective syntheses of structurally complicated natural products because of its high stereoselectivity and reactivity. Quinic acid (1) and its epimer 2 are versatile building blocks for the preparation of various bioactive compounds. We report the synthesis of methyl epi-anhydroquinate 3 via the [2,3]-sigmatropic rearrangement of iodosoalkene.

本文言語English
ページ(範囲)1273-1275
ページ数3
ジャーナルChemistry Letters
42
10
DOI
出版ステータスPublished - 2013

ASJC Scopus subject areas

  • 化学 (全般)

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