Synthesis of organometallic conducting polymers using soluble poly(n-alkylphenylene)s as ligands

H. Nishihara, H. Funaki, T. Shimura, K. Aramaki

研究成果: Conference article査読

12 被引用数 (Scopus)


Homogeneous reaction of soluble poly(n-hexylphenylene) (PHP) with a molybdenum carbonyl complex, (py)3Mo(CO)3, afforded an organometallic π-conjugated polymer at ambient temperature. The product was soluble in common organic solvents such as chloroform or THF and its infrared and UV-visible absorption spectra and electrochemical properties indicated a formation of (η6-arene)Mo(CO)3-type complex polymer, PHP-Mo(CO)3. The ratio of Mo(CO)3 units to benzene rings in PHP-Mo(CO)3 was estimated at 1/5 from the ratio of ν(C≡O) and ν(C = C) peak absorbances in the infrared spectrum and by the colorimetric analysis of Mo content. Reaction of poly(n-butylphenylene) (PBP) with chromium hexacarbonyl also afforded a organometallic polymer containing Cr(CO)3 moieties, PBP-Cr(CO)3. Conductivity of PHP-Mo(CO)3 and PBP-Cr(CO)3 was higher than that of free PHP and PBP, respectively, in the neutral state, although the activation energy for the conductivity is not seriously changed by the complex formation.

ジャーナルSynthetic Metals
2 -3 pt 2
出版ステータスPublished - 1993 1月 1
イベントProceedings of the International Conference on Science and Technology of Metals - ICSM'92 - Goteborg, Swed
継続期間: 1992 8月 121992 8月 18

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学


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