2-(Thieno[3,4-d]imidazol-2-yl)-1,3-dihydro-4,4,5,5-tetramethylimidazoline-1- oxyl-3-oxide (2) was designed and synthesized. Compound 2 was stable in a solid state but unstable in organic solvents. Solution ESR spectra showed that small spin densities locate on the four methyl groups and the thieno[3,4- d]imidazole ring, though most of spin densities localized on the ONCNO moiety. Magnetic susceptibility measurement showed that antiferromagnetic interaction is dominant which could be fitted to the Bonner-Fisher model with J = -8.8 cm-1.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry