Synthesis, Structures, and Photophysical Properties of Alternating Donor–Acceptor Cycloparaphenylenes

Shuhei Nishigaki, Miho Fukui, Haruki Sugiyama, Hidehiro Uekusa, Susumu Kawauchi, Yu Shibata, Ken Tanaka

研究成果: Article査読

19 被引用数 (Scopus)

抄録

The synthesis of alternating donor–acceptor [12] and [16]cycloparaphenylenes (CPPs) has been achieved by the rhodium-catalyzed intermolecular cross-cyclotrimerization followed by imidation and/or aromatization. These alternating donor–acceptor CPPs showed positive solvatofluorochromic properties and smaller HOMO–LUMO gaps compared with nonfunctionalized CPPs, which was confirmed by the theoretical study.

本文言語English
ページ(範囲)7227-7231
ページ数5
ジャーナルChemistry - A European Journal
23
30
DOI
出版ステータスPublished - 2017 5 29
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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