Synthetic studies on polymaxenolides: Synthesis and structure elucidation of nominal epoxyafricanane and other africane-type sesquiterpenoids

Yutaka Matsuda, Yusuke Endo, Yoko Saikawa, Masaya Nakata

研究成果: Article査読

14 被引用数 (Scopus)

抄録

A racemic total synthesis of the sesquiterpenoid unit of the hybrid marine natural product polymaxenolide has been achieved based on a three-component assembly followed by ring-closing metathesis as the key steps. However, the spectral data of our product synthesized from Δ 9(15)-africanene by epoxidation were not identical with those of the natural product named epoxyafricanane. The structure confirmation of the synthetic nominal epoxyafricanane is described.

本文言語English
ページ(範囲)6258-6263
ページ数6
ジャーナルJournal of Organic Chemistry
76
15
DOI
出版ステータスPublished - 2011 8 5

ASJC Scopus subject areas

  • 有機化学

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