The aldol type reaction catalyzed by arylmalonate decarboxylase - A decarboxylase can catalyze an entirely different reaction, aldol reaction

Yosuke Terao, Kenji Miyamoto, Hiromichi Ohta

研究成果: Article査読

15 被引用数 (Scopus)

抄録

The catalytic promiscuity of AMDase was demonstrated using a well-designed substrate based on the consideration of the reaction mechanism. As the reaction catalyzed by AMDase is supposed to proceed via an enolate intermediate, we expected that the enzyme promotes the aldol type reaction when an acceptor is properly arranged, which turned out to be true.

本文言語English
ページ(範囲)420-421
ページ数2
ジャーナルChemistry Letters
36
3
DOI
出版ステータスPublished - 2007 3 5

ASJC Scopus subject areas

  • Chemistry(all)

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