The local structure in heavily boron-doped diamond and the effect this has on its electrochemical properties

Takeshi Watanabe, Satoru Yoshioka, Tomokazu Yamamoto, Hossein Sepehri-Amin, Tadakatsu Ohkubo, Syo Matsumura, Yasuaki Einaga

研究成果: Article

10 引用 (Scopus)

抄録

Transmission electron microscopy (TEM) coupled with electron energy loss spectroscopy (EELS), and first principles calculations of EEL spectra were utilized to elucidate the relationship between the microscopic structure and the electrochemical properties of heavily boron-doped diamond (h-BDD). The electrochemical properties of h-BDD containing 1 at.% and 3 at.% boron are very different. TEM observations showed that 1 at.% h-BDD consists of small densely packed diamond crystallites, while 3 at.% h-BDD contains small voids and a graphite phase partly along the grain boundaries. The EEL spectrum of the grain interior in 1 at.% h-BDD and comparison of this with a theoretical spectrum shows that the boron atoms are mostly dispersed as single isolated substitutional atoms on diamond lattice sites in the grain interior and that only a small amount of sp2-bonded carbon is present. In contrast, in the grain interior of 3 at.% h-BDD, the boron atoms are mostly associated with nearest neighbor boron pairs, and consequently sp2-bonded carbon is formed. Thus, the local structure has a significant effect on the amount of sp2-bonded carbon. The quite different electrochemical properties of the samples are ascribed to the amount of sp2-bonding arising from the different local structures.

元の言語English
ページ(範囲)333-342
ページ数10
ジャーナルCarbon
137
DOI
出版物ステータスPublished - 2018 10 1

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Diamond
Boron
Electrochemical properties
Diamonds
Carbon
Atoms
Transmission electron microscopy
Graphite
Electron energy loss spectroscopy
Crystallites
Grain boundaries

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

The local structure in heavily boron-doped diamond and the effect this has on its electrochemical properties. / Watanabe, Takeshi; Yoshioka, Satoru; Yamamoto, Tomokazu; Sepehri-Amin, Hossein; Ohkubo, Tadakatsu; Matsumura, Syo; Einaga, Yasuaki.

:: Carbon, 巻 137, 01.10.2018, p. 333-342.

研究成果: Article

Watanabe, T, Yoshioka, S, Yamamoto, T, Sepehri-Amin, H, Ohkubo, T, Matsumura, S & Einaga, Y 2018, 'The local structure in heavily boron-doped diamond and the effect this has on its electrochemical properties', Carbon, 巻. 137, pp. 333-342. https://doi.org/10.1016/j.carbon.2018.05.026
Watanabe T, Yoshioka S, Yamamoto T, Sepehri-Amin H, Ohkubo T, Matsumura S その他. The local structure in heavily boron-doped diamond and the effect this has on its electrochemical properties. Carbon. 2018 10 1;137:333-342. https://doi.org/10.1016/j.carbon.2018.05.026
Watanabe, Takeshi ; Yoshioka, Satoru ; Yamamoto, Tomokazu ; Sepehri-Amin, Hossein ; Ohkubo, Tadakatsu ; Matsumura, Syo ; Einaga, Yasuaki. / The local structure in heavily boron-doped diamond and the effect this has on its electrochemical properties. :: Carbon. 2018 ; 巻 137. pp. 333-342.
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abstract = "Transmission electron microscopy (TEM) coupled with electron energy loss spectroscopy (EELS), and first principles calculations of EEL spectra were utilized to elucidate the relationship between the microscopic structure and the electrochemical properties of heavily boron-doped diamond (h-BDD). The electrochemical properties of h-BDD containing 1 at.{\%} and 3 at.{\%} boron are very different. TEM observations showed that 1 at.{\%} h-BDD consists of small densely packed diamond crystallites, while 3 at.{\%} h-BDD contains small voids and a graphite phase partly along the grain boundaries. The EEL spectrum of the grain interior in 1 at.{\%} h-BDD and comparison of this with a theoretical spectrum shows that the boron atoms are mostly dispersed as single isolated substitutional atoms on diamond lattice sites in the grain interior and that only a small amount of sp2-bonded carbon is present. In contrast, in the grain interior of 3 at.{\%} h-BDD, the boron atoms are mostly associated with nearest neighbor boron pairs, and consequently sp2-bonded carbon is formed. Thus, the local structure has a significant effect on the amount of sp2-bonded carbon. The quite different electrochemical properties of the samples are ascribed to the amount of sp2-bonding arising from the different local structures.",
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AU - Ohkubo, Tadakatsu

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