Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer

Akane Kozuma, Keiichi Komatsuki, Kodai Saito, Tohru Yamada

研究成果: Article

抄録

Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.

元の言語English
ページ(範囲)60-63
ページ数4
ジャーナルChemistry Letters
49
発行部数1
DOI
出版物ステータスPublished - 2020 1 1

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Chirality
Carbonates
Cyclization
Lewis Acids
Catalysts
Hot Temperature
cyclopentenone

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer. / Kozuma, Akane; Komatsuki, Keiichi; Saito, Kodai; Yamada, Tohru.

:: Chemistry Letters, 巻 49, 番号 1, 01.01.2020, p. 60-63.

研究成果: Article

Kozuma, Akane ; Komatsuki, Keiichi ; Saito, Kodai ; Yamada, Tohru. / Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer. :: Chemistry Letters. 2020 ; 巻 49, 番号 1. pp. 60-63.
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