Thermodynamic Properties of Ionic Semiclathrate Hydrate Formed with Tetrabutylammonium Propionate

Yuji Yamauchi, Tatsuro Yamasaki, Fuyuaki Endo, Atsushi Hotta, Ryo Ohmura

研究成果: Article査読

16 被引用数 (Scopus)

抄録

The phase equilibrium temperature and dissociation heat of tetrabutylammonium propionate (TBAPr) hydrate are reported. TBAPr hydrate is a type of ionic semiclathrate hydrates and also could potentially be used as thermal energy storage material. The temperature-composition phase diagram of the TBAPr hydrate was determined in a defined range of mass fractions. Considering the dissociation heat of differential scanning calorimetry (DSC) measurements, multiple peaks of heat flow were observed in the TBAPr-water system at the TBAPr mass fraction lower than 0.35, and there was a single peak at the mass fraction higher than 0.37.

本文言語English
ジャーナルChemical Engineering and Technology
DOI
出版ステータスAccepted/In press - 2017

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)
  • 産業および生産工学

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