Thermoelectromotive force of some redox couples in an amide-type room-temperature ionic liquid

Tsubasa Migita, Naoki Tachikawa, Yasushi Katayama, Takashi Miura

研究成果: Article査読

44 被引用数 (Scopus)

抄録

Reaction entropies of some metal complex redox couples in an amide-type room-temperature ionic liquid, 1-butyl-lmethylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) have been estimated by measuring the thermoelectromotive force at a non-isothermal cell. It is suggested that the reaction entropy is dependent on the difference in the charge densities of the oxidant and reductant of a redox couple, probably related to the coulombic interaction between the redox species and the ions composing the ionic liquid.

本文言語English
ページ(範囲)639-641
ページ数3
ジャーナルElectrochemistry
77
8
DOI
出版ステータスPublished - 2009 8

ASJC Scopus subject areas

  • Electrochemistry

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