Total Synthesis of Biselyngbyaside

Eisuke Sato, Miho Sato, Yurika Tanabe, Naoya Nakajima, Akifumi Ohkubo, Kiyotake Suenaga

研究成果: Article査読

11 被引用数 (Scopus)

抄録

The first total synthesis of biselyngbyaside, an 18-membered macrolide glycoside, was achieved. The glycoside bond was introduced using the Schmidt method before construction of the 18-membered ring due to the instability of the conjugated diene and the β-hydroxy ester moiety. The macrolactone ring was constructed using the Mitsunobu reaction followed by intramolecular the Stille coupling reaction.

本文言語English
ページ(範囲)6770-6777
ページ数8
ジャーナルJournal of Organic Chemistry
82
13
DOI
出版ステータスPublished - 2017 7月 7

ASJC Scopus subject areas

  • 有機化学

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